Paper Title
Bioinorganic [Zn(II)-antibiotics-phenacetin] complex at thermodynamic parameter by polarographic technique
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Authors
Amul Kumar Kesharwani , Prof. Farid khan
Keywords
Abstract
Thermodynamic parameters and kinetic parameters of Zn (II) complexes with neomycin, chlortetracycline, oxytetracycline, tetracycline, penicillin-V and penicillin-G as primary ligands and phenacetin as secondary ligand were determined by polarographic technique and it is observed that the half wave potential increased with increase in the concentrations of secondary ligand phenacetin showing the formation of ternary complex of zinc metal with penicillin-G and phenacetin. The values of standard rate constant (k) of Zn and its complexes are found to be order of 10-3 cm. sec-1, confirming that the electrode processes are quasi reversible. The value of charge transfer coefficient (α), comes about 0.500. The values obtained of ΔS are found to be more negative at higher temperature confirmed that the complex are not stable at higher temperature. The values of stability constants obtained are not high and the study showed that the complexes are not stable at higher temperature.
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Amul Kumar Kesharwani & Prof. Farid khan (May-2022). Bioinorganic [Zn(II)-antibiotics-phenacetin] complex at thermodynamic parameter by polarographic technique . INTERNATIONAL JOURNAL OF NOVEL RESEARCH AND DEVELOPMENT, 7(5), 1166-1170. https://ijnrd.org/papers/IJNRD2205154.pdf
Issue
Volume 7 Issue 5, May-2022
Pages : 1166-1170
Other Publication Details
Paper Reg. ID: IJNRD_181108
Published Paper Id: IJNRD2205154
Downloads: 000121977
Research Area: Chemistry
Country: Sagar, Madhya Pradesh, India
Published Paper PDF: https://ijnrd.org/papers/IJNRD2205154.pdf
Published Paper URL: https://ijnrd.org/viewpaperforall?paper=IJNRD2205154
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Journal Name: INTERNATIONAL JOURNAL OF NOVEL RESEARCH AND DEVELOPMENT(IJNRD)
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